Mechanism and Inhibition of Oxygen Reduction on Light Weight Alloys

Abstract

Inhibition of oxygen reduction is a very effective means for reducing corrosion of Al alloys and many other materials. The oxygen reduction reaction is quite complex, and very dependent on the existence of catalytic sites on the metallic surface. Recent projects on Al corrosion and inhibition have identified the importance of oxygen reduction, but have not elucidated the mechanism or the most effective means for its inhibition. The work proposed herein is not intended to comprehensively examine oxygen reduction, but it is directed toward identifying which aspects of an alloy promote O2 reduction. Once the nature of catalytic sites is understood, it should be possible to rationally select inhibitors that are effective for corrosion protection, as well as cost effective and environmentally more benign than chromate.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2006
Accession Number
ADA456215

Entities

People

  • Gerald S. Frankel
  • Richard Mccreery

Organizations

  • Ohio State University

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms

DTIC Thesaurus Topics

  • Alloys
  • Chemical Compounds
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Chromium Compounds
  • Corrosion
  • Corrosion Inhibition
  • Inhibition
  • Inhibitors
  • Magnetic Resonance
  • Materials
  • Materials Science
  • Nuclear Magnetic Resonance
  • Oxidation Reduction Reactions
  • Vanadium
  • Vanadium Compounds

Readers

  • Materials Science and Engineering.
  • Organic Chemistry
  • Systems Analysis and Design