Elaboration and Characterization of Nano-Sized AlxMoyOz/Al Thermites

Abstract

A new process to control the reactivity of thermites containing molybdenum trioxide (MoQ3) and aluminium (Al) has been developed at the Institut franco-allemand de recherches de Saint Louis (ISL). This process consists of a new sol-gel method nano-sized mixed AlxMoyOz phases whose structure is correlated to the chemical composition. It is possible to adjust the energetic properties of the thermites obtained through physical mixing of these phases with nano-sized aluminium (Al 50-P, Nanotechnologies). The resulting nano-thermites are very insensitive to mechanical and thermal stresses, but can be easily ignited by the energy brought by a laser beam. The nano-structuring of the oxidative phase decreases the sensitivities, shortens the ignition delay times and dramatically increases the combustion rates. These promising characteristics allow considering these metastable interstitial composites (MICs) as potential components for insensitive weapon ignition systems.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2006
Accession Number
ADA456236

Entities

People

  • D. Spitzer
  • M. Comet

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Aluminum
  • Burning Rate
  • Chemical Composition
  • Chemical Reaction Properties
  • Combustion
  • Composite Materials
  • Electron Microscopy
  • Energetic Materials
  • Ignition
  • Ignition Lag
  • Ignition Systems
  • Laser Beams
  • Lasers
  • Materials
  • Mixtures
  • Molybdenum
  • Thermal Stresses

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Small Business Innovation Research Program (SBIR) EDI Research and Innovation.
  • Thin Film Deposition Science.

Technology Areas

  • Biotechnology
  • Directed Energy