The Effects of Colloidal Processing on the Densification of Titanium Diboride (TiB2) - Alumina (Al2O3) Composites

Abstract

Titanium diboride/Alumina (TiB2/Al2O3) powders produced using self-propagating high-temperature synthesis (SHS) can be hot pressed into armor tiles that exhibit superior resistance to penetration as compared to TiB2, SiC, B4C or Al2O3. As with other advanced ceramics however, difficulties in processing TiB2/Al2O3 arise from the inability to reproduce specimens having identical microstructure and properties. Since the SHS powders are available commercially, the interactions between TiB2 and Al2O3 have been analyzed with respect to their colloidal properties, as measured by their respective zeta potentials, density, volume fraction, and particle size. A comparison of colloidal properties, green and sintered densities and microstructure of Composite SHS TiB2/Al2O3 and SHS TiB2 with commercially available Aluminas has been completed. Although SuspensionStability(copyright) predicts the colloidal behavior of SHS TiB2 in Alumina, the SHS Composite powders seem to be insensitive to colloidal processing, and the continuous microstructure associated with penetration resistance is predominantly characteristic of SHS Composite TiB2/Al2O3 starting powders.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 2000
Accession Number
ADA457276

Entities

People

  • Ernest Chin
  • Gary Gilde
  • Lisa P. Franks
  • Melissa J. Crimp

Organizations

  • Tank-automotive and Armaments Command

Tags

DTIC Thesaurus Topics

  • Composite Materials
  • Foreign Intelligence
  • High Temperature
  • Microstructure
  • Operations Security
  • Particle Size
  • Particles
  • Resistance
  • Security
  • Silicon Carbide
  • Technical Ceramics
  • Titanium

Fields of Study

  • Materials science

Readers

  • Powder metallurgy of Titanium alloys.