Spectral and Time-Resolved Photoluminescence Studies of Eu-Doped GaN

Abstract

We report on spectral and time-resolved photoluminescence (PL) studies performed on Eu-doped GaN prepared by solid-source molecular-beam epitaxy. Using above-gap excitation, the integrated PL intensity of the main Eu3+ line at 622.3 nm (5D0->7F2 transition) decreased by nearly 90% between 14 K and room temperature. Using below-gap excitation, the integrated intensity of this line decreased by only ~50% for the same temperature range. In addition, the Eu31 PL spectrum and decay dynamics changed significantly compared to above-gap excitation. These results suggest the existence of different Eu31 centers with distinct optical properties. Photoluminescence excitation measurements revealed resonant intra-4f absorption lines of Eu3+ ions, as well as a broad excitation band centered at ;400 nm. This broad excitation band overlaps higher lying intra-4f Eu3+ energy levels, providing an efficient pathway for carrier-mediated excitation of Eu3+ ions in GaN.

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Document Details

Document Type
Technical Report
Publication Date
Mar 17, 2003
Accession Number
ADA457837

Entities

People

  • A. J. Steckl
  • D. S. Lee
  • Ei E. Nyein
  • J. Heikenfeld
  • J. M. Zavada
  • U. Hömmerich

Organizations

  • Hampton University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Argon Lasers
  • Band Gaps
  • Chemical Vapor Deposition
  • Conduction Bands
  • Emission
  • Energy
  • Energy Bands
  • Energy Levels
  • Energy Transfer
  • High Resolution
  • Materials
  • Measurement
  • Optical Properties
  • Photoluminescence
  • Physics
  • Spectra
  • Transitions

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Semiconductor Device Technology