Aluminum Nitride Substrate Growth by Halide Vapor Transport Epitaxy

Abstract

High-quality AlN layers with thickness up to 50 micrometers have been grown by HVTE at growth rates up to 60 micrometers/h at deposition temperatures of 1000-1100 degrees C in the pressure range of 50-760 Torr. The HVT process uses an aluminum chloride amine adduct as the aluminum source and ammonia for the nitrogen. This new technique eliminates the main difficulties of the conventional HVPE growth, where aluminum oxidation and the strong reactivity of aluminum chloride with quartz create the potential for oxygen contamination. The crystalline layer quality as determined by X-ray rocking curve measurement shows FWHM of 300-900 and 500-1300 arcsec for (002) and (102) planes, respectively.

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Document Details

Document Type
Technical Report
Publication Date
Jan 31, 2003
Accession Number
ADA460001

Entities

People

  • D. F. Bliss
  • D. Weyburne
  • J. S. Bailey
  • Vladimir L. Tassev

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Air Platforms
  • Sensors

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Aluminum
  • Aluminum Nitrides
  • Chlorides
  • Contamination
  • Crystal Growth
  • Crystals
  • Elements
  • Epitaxial Growth
  • Halides
  • Materials
  • Measurement
  • Microscopes
  • Military Research
  • Nitrogen
  • Nitrogen Compounds
  • X Rays

Fields of Study

  • Materials science

Readers

  • Organic Chemistry
  • Semiconductor Device Technology
  • Thin Film Deposition Science.