Power and Thermal Technologies for Air and Space. Delivery Order 0001: Single Ionic Conducting Solid-State Electrolyte

Abstract

This report focuses on the development of a lithium-ion conducting channel as a solid-state electrolyte for rechargeable lithium batteries through the use of thin films of dilithium phthalocyanine (Li2Pc) which have been solvent cast onto manganese dioxide cathodes. Experimental procedures have been developed which have resulted in the successful deposition of Li2Pc with low ionic resistance. AC impedance measurements and analysis of the equivalent circuit has shown that specific ionic conductivities of 1.9 x 10-4 S/cm at room temperature are achievable. However, it has also been shown that Li2Pc in its current configuration is also an electronic conductor. Development of a thin film insulator based on lithium nitride in conjunction with Li2Pc is now in progress.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 2005
Accession Number
ADA460518

Entities

People

  • Allen Turner

Organizations

  • University of Dayton

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Chemical Reactions
  • Conductivity
  • Crystals
  • Electrochemical Cells
  • Electrolytes
  • Equivalent Circuits
  • Films
  • Government Procurement
  • Impedance
  • Materials
  • Metals
  • Phthalocyanines
  • Resistance
  • Thin Films
  • Vapor Deposition

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Electronics Engineering

Technology Areas

  • Microelectronics
  • Space
  • Space - Hall-Effect Thruster