Characterization and Neutralization of Recovered Lewisite Munitions

Abstract

This report summarizes efforts to characterize the lewisite contained in recovered munitions and validate a neutralization chemistry for lewisite fill materiel. The selected neutralization reagent, aqueous 20 wt% sodium permanganate, was found to be effective in destroying the lewisite. In lab-scale and full-scale Explosive Destruction System testing, the aqueous permanganate consistently produced terminal neutralents that had residual lewisite levels well below the treatment goal of 50 mg/L (ppm). The reaction products included inorganic pentavalent arsenate and various pentavalent organo-arsenicals. Solid manganese dioxide was also produced during the reaction and was successfully managed in the full-scale Explosive Destruction System testing.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 2006
Accession Number
ADA460761

Entities

People

  • Amanda M. Schenning
  • Frederic J. Berg
  • H. D. Durst
  • Janet C. Fouse
  • Jill L. Ruth
  • Kevin M. Morrissey
  • Leslie R. Mcmahon
  • Lucille P. Forrest
  • Mary P. Weiss
  • Melissa S. Hulet
  • Richard J. O'connor
  • Richard L. Cheicante
  • William R. Creasy

Organizations

  • Leidos

Tags

Communities of Interest

  • Biomedical
  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Buffers (Chemistry)
  • Capillary Electrophoresis
  • Chemical Synthesis
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Chemistry
  • Organic Chemistry

Readers

  • Canadian European Scientific Immigration and Epilepsy Clearance Studies
  • Environmental Engineering
  • Surface Engineering/Surface Coating Technology.