Protein Adducts of the Prostate Carcinogen PhlP in Children

Abstract

The goal of this project is to develop an assay to measure the binding a common food-borne carcinogen (PhIP)to human serum albumin (HSA) an abundant protein in blood that frequently binds to small molecules in the blood stream. Measurement of HSA-bound PhIP may allow determination of the exposure (dosimetry) of large populations of humans to PhIP. Such critical data are almost never included in epidemiology studies owing to low detection sensitivity of current methods. Based upon our earlier results in humans demonstrating that PhIP binds to HSA we are developing an ultrasensitive mass spectrometry assay that depends upon competitive binding of adducted HSA to an antibody saturated with a radiocarbon labeled PhIP-bound peptide. This assay will allow quantitative measurement with the naturally occurring substrate from archived human samples. We report progress towards antibody development that will enable the assay to be realized.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 2006
Accession Number
ADA462546

Entities

People

  • Paul T. Henderson

Organizations

  • University of California

Tags

DTIC Thesaurus Topics

  • Albumins
  • Amino Acids
  • Antibodies
  • Carcinogens
  • Chemistry
  • Detection
  • Environmental Health
  • Mass Spectrometers
  • Mass Spectrometry
  • Measurement
  • Molecules
  • Neoplasms
  • Peptides
  • Prostate Cancer
  • Proteins
  • Small Molecules
  • Spectrometry

Fields of Study

  • Biology

Readers

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