Investigation of Kinetics of Iso-Octane Ignition Under Scramjet Conditions (Postprint)

Abstract

A single pulse reflected shock tube was used to investigate iso-octane ignition over the temperature range of 900-1400 K at a pressure of ~1 atm. To account for the anticipated long ignition delay times at the lower temperatures, long shock tube dwell times (~12 ms) at lower temperature and near atmospheric pressure were achieved by using argon-helium mix as a driver gas. Chemical thermometer experiments were conducted to remove any uncertainties in determining post-reflected shock temperatures. The ignition delay data obtained in this study are in good agreement (in the overlap region) with the iso-octane ignition data from a previous shock tube study. However, the activation energy of iso-octane ignition obtained in this study in the lower temperature region (<1300 K) is significantly smaller (~15 kcal vs. ~40 kcal) than that obtained in a previous higher temperature study. The deflagration may be responsible for lowering of activation energy under the conditions of this study. The AFRL mechanism showed a good agreement with measured ignition delays while a second mechanism (Curran et al.) showed poorer agreement.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 2006
Accession Number
ADA464398

Entities

People

  • Campbell D. Carter
  • Moshan S. Kahandawala
  • Shehan A. Corera
  • Skip Williams
  • Sukh S. Sidhu

Organizations

  • University of Dayton

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Alkanes
  • Barometric Pressure
  • Chemistry
  • Combustion
  • Deflagration
  • Detection
  • Dwell Time
  • Heat Of Activation
  • Hydrocarbon Fuels
  • Ignition
  • Ignition Lag
  • Low Temperature
  • Pressure Transducers
  • Shock Tubes
  • Supersonic Combustion Ramjet Engines
  • Time Intervals

Readers

  • Combustion Dynamics and Shock Wave Physics.
  • Combustion science or combustion engineering.
  • Mathematics or Statistics