Synthesis of Organotin Polymers by Poly-Addition

Abstract

The results of a synthetic program directed towards the preparation of IVth main group organometallic polymers are presented. The main body of the report is concerned with the synthesis of linear polymers having a carbon chain regularly interrupted by tin (and in some cases other IVth group) atoms Such polymers have been obtained by means of true poly-addition reactions (hydrogen transfer polymerization) involving an organotin dihydride and either a dienic or a diynic or a monoyni C coumpound The synthesis of lVth group organometal-substituted polystyrenes carbon chain polymers containing the organometallic moiety as a substituent group as well as of a series of poly-p-phenylenesilanes-polymers consisting of chains of p-phenylene groups connected by dialkyl(aryl) silane groups are dealt with briefly.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1962
Accession Number
ADA470439

Entities

People

  • G. J. Van Der Kerk
  • J. G. Noltes

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  • Abstracts
  • Addition Reactions
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Fields of Study

  • Chemistry

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  • Polymer Science and Technology