Bonding in Inorganic Systems

Abstract

Evidence from nuclear magnetic resonance studies for pi -bonding between boron and nitrogen in the borazens is presented. Preliminary experiments, by infrared spectroscopy which indicate that a similar situation might exist between phosphorus (III) and nitrogen, in open chain compounds, are also reported. The energy barrier to rotation about the BN bond in dimethylaminophenylchloroborane is calculated (from four different observations on the N.M.R. spectra) as 18 plus or minus 2 kcals. Exploratory measurements on certain boron-oxygen compounds are also presented.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1962
Accession Number
ADA470475

Entities

People

  • Jung‐Hee Lee
  • M. F. Lappert
  • P. A. Barfield

Organizations

  • Manchester University

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Elements
  • Information Operations
  • Infrared Spectroscopy
  • Magnetic Resonance
  • Nitrogen
  • Nuclear Magnetic Resonance
  • Oxygen Compounds
  • Resonance
  • Spectra
  • Spectroscopy

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry
  • Quantum Chemistry