Room-Temperature, Near IR Fluorescence of High Optical Quality KTP (Postprint)

Abstract

We investigated room temperature fluorescence in the 500-900nm spectral region from high optical quality, polished and uncoated KTP crystals from three different commercial vendors. The crystals were all cut into 5x5x5 mm3 cubes with their dielectric axes along the cube edges. The pump source was a tripled Nd:YAG laser operating at 355nm and 7mJ energy having 3ns pulse width and 100Hz pulse repetition rate. Samples from two vendors showed low fluorescence of similar magnitude while samples from the third vendor showed nearly two orders of magnitude higher value in the peak fluorescence near 800nm. In addition, all samples showed a weaker secondary fluorescence band peaking near 600nm. A low fluorescence sample from one of the vendors also showed typical "gray tracking" at these pump radiation conditions. We have also measured lifetimes of 2.9 +/- 0.7 us and 4.9 +/- 0.1 us for the centers responsible for fluorescence near 845nm and 595nm respectively in the KTP sample showing highest fluorescence and "gray tracking" in this group of samples. The manufacturing processes used to produce high optical quality and low fluorescence KTP materials are proprietary to the commercial vendors and were not provided. Possible sources of fluorescence in these materials are discussed.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 2007
Accession Number
ADA472338

Entities

People

  • D. E. Zelmon
  • K. L. Schepler
  • R. D. Peterson
  • S. M. Hegde

Organizations

  • University of Dayton

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Sensors

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Crystals
  • Detection
  • Detectors
  • Frequency
  • Laser Beams
  • Lasers
  • Materials
  • Military Research
  • Optical Materials
  • Optical Properties
  • Radiation
  • Scattering
  • Spectra
  • Spectroscopy
  • Universities

Fields of Study

  • Physics

Readers

  • Optical Physics and Photonics.
  • Spectroscopy.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition