Evaluation of Catalytic and Thermal Cracking in a JP-8 Fueled Pulsed Detonation Engine (Postprint)

Abstract

Pulsed detonation engines (PDEs) depend on rapid ignition and transition from deflagration to detonation. The prospect of converting the PDE from experimental to operational use necessitates a considerable reduction in the time required to ignite and detonate a liquid hydrocarbon fuel in air, such as JP-8. This research effort is focused on PDE operation enhancements using dual detonation tube, concentric-counter-flow heat exchangers to elevate the fuel temperature levels sufficiently to induce thermal cracking. Additionally, a zeolite catalytic coating is applied to the heat-exchanger surfaces to stimulate further cracking of the fuel and reduce coke deposition. To quantify the PDE performance, three parameters are examined: ignition time, deflagration-to-detonation transition (DDT) time, and DDT distance. Once cracked, the JP-8/air mixture results in a shorter ignition time, DDT time, and DDT distance for the majority of equivalence ratios, with a reduction in ignition time of up to 60% at 908 K, as compared to flash vaporized JP-8/air mixtures. Furthermore, both the ignition and detonability limits are expanded by cracking the fuel, with lean limits at an equivalence ratio of 0.75. Coke deposition found in the fuel filter consists of carbon as well as substantial concentrations of silicon and aluminum, due to breakdown of the silica-alumina zeolite structure. Additionally, poisoning of the catalyst is shown to occur after five hours of operation, although no degradation in performance was observed.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 2007
Accession Number
ADA473517

Entities

People

  • Frederick R. Schauer
  • John L. Hoke
  • Royce P. Bradley
  • Timothy M. Helfrich

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Alkanes
  • Alkenes
  • Catalysts
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Elements
  • Fuel Filters
  • Fuel Systems
  • Heat Exchangers
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Ignition
  • Turbines
  • United States

Readers

  • Organic Chemistry
  • Petroleum Engineering
  • Rocket Propulsion.