Tracking the Weathering of an Oil Spill with Comprehensive Two-Dimensional Gas Chromatography

Abstract

Comprehensive two-dimensional gas chromatography (GC x GC)was used to investigate the Bouchard 120 oil spill. The latter occurred on April 25, 2003, when the barge Bouchard 120 spilled <375,000 liters of No. 6 fuel oil into Buzzards Bay, Massachusetts. In order to gain a better understanding of the natural processes affecting the fate of the spilled product, we collected and analyzed oil-covered rocks from Nyes Neck beach in North Falmouth, Massachusetts. Here we discuss the data from samples collected on May 9, 2003, and six months later, on November 23, 2003. Along with standard two-dimensional gas chromatographic analysis, we employed unique data-visualization techniques such as difference, ratio, and addition chromatograms to highlight how evaporation, water washing, and biodegradation weathered the spilled oil. These approaches provide a new perspective to studying oil spills and aid attempts to remediate them.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2006
Accession Number
ADA478677

Entities

People

  • Brian M. Kile
  • Christopher M. Reddy
  • Desiree Plata
  • Glenn S. Frysinger
  • Li Xu
  • Richard B. Gaines
  • Robert K. Nelson
  • Sean P. Sylva
  • Stephen E. Reichenbach

Organizations

  • Woods Hole Oceanographic Institution

Tags

Communities of Interest

  • Autonomy
  • C4I
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Alkanes
  • Aromatic Hydrocarbons
  • Buzzards Bay
  • Chemical Synthesis
  • Chemistry
  • Chromatography
  • Complex Mixtures
  • Cyclic Hydrocarbons
  • Data Visualization
  • Fuel Oils
  • Gas Chromatography
  • Mass Spectrometry
  • Oil Spills
  • Organic Chemistry
  • Petroleum
  • Spectrometry
  • Two Dimensional

Fields of Study

  • Environmental science

Readers

  • Environmental Remediation and Restoration.
  • Marine Ecotoxicology