Nanoencapsulation of OPAA With Mesoporous Materials for Chemical Agent Decontamination in Organic Solvents

Abstract

Organophosphorus acid anhydrolase (OPAA) offers great potential for safe, non-corrosive decontamination of a wide range of organophosphorus compounds, including the fluoride containing chemical nerve agent Soman and Sarin. The nanoencapsulation of OPAA with mesoporous materials provides a very stable and convenient formulation for use in chemical agent detoxification. In the present study, the enzyme was prepared in both hydrophilic and hydrophobic matrices and measured for activity against diisopropyl fluorophosphate using a F-specific electrode. The enzyme activity in different matrices was evaluated in various organic solvents. Significant activities were retained in most of these matrices, particularly in the presence of acetone and dimethyl formamide. These findings suggested that the OPAA- mesoporous hybrid materials might be suitable for a wide variety of applications including large area and personnel decontamination, individual protection, and detection.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2003
Accession Number
ADA483485

Entities

People

  • H. Dong
  • K. K. Ong
  • Rui Yin
  • T-c Cheng
  • Yuting Wei

Organizations

  • Drexel University

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Compounds
  • Chemical Synthesis
  • Chemical Warfare Agents
  • Chemistry
  • Coding
  • Decontamination
  • Electrodes
  • Fluorides
  • Hydrolysis
  • Instructions
  • Materials
  • Nerve Agents
  • Organic Solvents
  • Organophosphorus Compounds
  • Polyethylene Glycols
  • Solvents

Readers

  • Analytical Chemistry