Novel Breast Cancer Therapeutics Based on Bacterial Cupredoxin

Abstract

The tumor suppressor p53 is a major player in cell growth, genomic stability and cell death. Recent in vivo work suggested that bacterial Pseudomonas aeruginosa azurin can enter cancer cells and interact with p53 promoting cell death. Despite being a novel concept to target cancer, there are no thermodynamic details known for the proposed azurin-p53 complex. This project aims to fill this gap by employing biophysical methods in conjunction with purified proteins in vitro to address four aims. We will reveal (1.) which p53 domain interacts with azurin and probe affinity and stoichiometry, (2.) the molecular mechanism by which azurin increases cellular levels of p53, (3.) the region on azurin that interacts with p53 and (4.) use the acquired information to propose smaller molecules that retain properties of azurin. During the year, several discoveries have been made: most importantly, azurin is found to bind to the unstructured N-terminal domain of p53 and a small 13-residue peptide is able to reproduce part of the azurin interaction. Better biophysical understanding of azurin's interaction with p53 in vitro may be the gateway to innovative treatments of cancer.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 2007
Accession Number
ADA484653

Entities

People

  • Pernilla Wittung-Stafshede

Organizations

  • Rice University

Tags

DTIC Thesaurus Topics

  • Amines
  • Bacterial Proteins
  • Breast Cancer
  • Cell Membrane
  • Cell Physiological Processes
  • Cells
  • Chemical Analysis
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Diseases And Disorders
  • Mass Spectrometry
  • Molecules
  • Neoplasms
  • Spectra
  • Spectroscopy

Fields of Study

  • Biology
  • Chemistry

Readers

  • Marine Ecotoxicology
  • Molecular Biology and Genetics
  • Systems Analysis and Design

Technology Areas

  • Biotechnology