Resonant Laser Ignition Study of HAN-HEHN Propellant Mixture (Preprint)

Abstract

Resonant laser ignition at wavelengths in the UV and IR was demonstrated for hydroxyl ammonium nitrate (HAN) - hydroxyethylhydrazinium nitrate (HEHN) mixtures. This prototypical ionic liquid propellant was successfully and reliably ignited/detonated under confinement with single laser pulses in the mid IR at 2.94 and 10.6 microns. UV wavelengths at 193 and 248 nm were also resonant with sample absorption but they did not lead to ignition with the available excimer laser pulse energies. The results are consistent with absorption of the IR laser pulse within a short path, efficient V-->T relaxation, and thermal decomposition of HAN that leads to additional chemical reaction and ignition/detonation of milligram samples within tens of microseconds.

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Document Details

Document Type
Technical Report
Publication Date
Jul 17, 2008
Accession Number
ADA485620

Entities

People

  • Angelo J. Alfano
  • Ghanshyam L Vaghjiani
  • Jeffrey D. Mills

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption
  • Air Force Research Laboratories
  • Ammonium Nitrate
  • Carbon Dioxide Lasers
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Decomposition
  • Excimer Lasers
  • Ignition
  • Laser Ignition Systems
  • Laser Pulses
  • Lasers
  • Light (Electromagnetic Radiation)
  • Materials Laboratories
  • Propellants
  • Rocket Oxidizers

Fields of Study

  • Physics

Readers

  • Aquatic Ecology
  • Combustion science or combustion engineering.
  • Optical Physics and Photonics.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers