SSMAS NMR Study of HD, GD, and VX on Carbon Fiber Textiles for Wipes

Abstract

The C13 and P31 SSMAS NMR were used to study the degradation of HD, GD, and VX on a mesoporous and a microporous carbon fiber textile. The degradation of HD was faster than on ambient sand, concrete, limestone, and asphalt, and comparable to moist sand, concrete, limestone, and asphalt, forming toxic H-2TG and non-toxic TDG. The HD absorbed on both fiber textiles. The VX degradation rate on the carbon fiber textiles was comparable to sand, although the product was the toxic compound diethyl dimethylpyrophosphonate, rather than non-toxic ethyl methylphosphonic acid, as on sand. The VX absorbed on the mesoporous, but not the microporous fiber textiles. The GD absorbed into the fiber textiles and degraded to non-toxic ethyl methylphosphonic acid within a week.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 2008
Accession Number
ADA485697

Entities

People

  • Brian K. Maciver
  • Carol A. Brevett
  • Dennis K. Rohrbaugh
  • Kenneth B. Sumpter

Organizations

  • Leidos

Tags

Communities of Interest

  • Counter WMD
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Carbon Fibers
  • Chromatography
  • Concrete
  • Degradation
  • Fibers
  • Gas Chromatography
  • Instrumentation
  • Liquid Chromatography
  • Liquids
  • Mass Spectrometry
  • Materials
  • Physical Properties
  • Relaxation Time
  • Spectra
  • Spectrometry
  • Standards
  • Textiles

Readers

  • Analytical Chemistry
  • Nanocomposite Materials Science
  • Pavement Materials Engineering.