Liquid Azide Salts

Abstract

Ionic liquid azides from azidoethyl, alkyl and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles, were prepared and examined for the first time in order to investigate their structural and physical properties. All reported salts possess melting points below 100 deg C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. The presence of quaternary nitrogen confers both thermal stability and negligible volatility.

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Document Details

Document Type
Technical Report
Publication Date
Sep 13, 2007
Accession Number
ADA489371

Entities

People

  • Adam Brand
  • Ashwani Vij
  • Greg Warmoth
  • Jeffrey Mills
  • Leslie Hudgens
  • Michael Rosander
  • Stefan Schneider
  • Tommy Hawkins

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Air Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Alcohols
  • Chemical Synthesis
  • Chemistry
  • Crystal Lattices
  • Crystal Structure
  • Energetic Materials
  • Inorganic Chemistry
  • Ionic Liquids
  • Melting Point
  • Organic Chemistry
  • Phase Transformations
  • Physical Properties
  • Raman Spectra
  • Raman Spectroscopy
  • Spectroscopy
  • Thermal Stability

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry