Rearrangement of 3-Membered 1,1,2-Trifluorobromonium and Iodonium Ions and Comparison of Trifluorochloronium to Fluorocarbeniuim Ions (Postprint)

Abstract

In this paper we investigate the influence that a 4-halosubstituent has on formation of three-membered halonium ions and their rearrangement to five-membered ring intermediates when chloronium, bromonium and iodonium ions from alkenes 1, 2 and 3 are formed in aprotic solvent (Scheme 1). We also compare the open-ion chloronium ions with the open-carbocations from addition of a proton to terminal fluorosubstituted alkenes.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2008
Accession Number
ADA490473

Entities

People

  • D. Shellhamer
  • H. Forberg
  • J. Boatz
  • K. Davenport
  • M. Herrick
  • N. Trager
  • R. Jason Jones
  • R. Weiss
  • S. Consuegra Rodŕıguez
  • S. Sanabria
  • V. Heasley

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Acids
  • Air Force
  • Air Force Research Laboratories
  • Alkenes
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Chlorination
  • Chlorine
  • Halogens
  • Hydrocarbons
  • Organic Chemistry
  • Terminals

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry