Evaluation of MOF-74, MOF-177, and ZIF-8 for the Removal of Toxic Industrial Chemicals

Abstract

Current technology-based efforts are focusing on a nanotechnology approach to sorbent development for air purification applications. Metal-organic frameworks (MOFs) and zeolitic imidazolate frameworks (ZIFs) are two novel classes of materials that allow for specific functionalities to be designed directly into a porous framework. This report is the second in a series of summary reports based on the evaluation of samples from the University of California, Los Angeles. The samples evaluated in this report are a continuation of a baseline series of materials aimed at collecting design rules for future materials; results from this and the previous report will be used to create a second-generation of reactive MOFs and ZIFs for air purification applications. Testing of the novel materials included nitrogen isotherm data, water, and chloroethane adsorption equilibria, and ammonia, cyanogen chloride and sulfur dioxide breakthrough data.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 2008
Accession Number
ADA491496

Entities

People

  • Alex Balboa
  • Christopher J. Karwacki
  • George Wagner
  • Gregory W. Peterson
  • John Mahle
  • Tara Sewell

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Counter WMD
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Adsorption
  • Chemical Reactions
  • Chloroethanes
  • Cyanides
  • Dielectric Gases
  • Flow Rate
  • Isotherms
  • Mass Transfer
  • Materials
  • Nitrogen Compounds
  • Packing Density
  • Physical Properties
  • Porous Materials
  • Sorption
  • Test And Evaluation
  • Test Methods
  • Three Dimensional

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Nanocomposite Materials Science
  • Software Engineering

Technology Areas

  • Biotechnology