Synthesis, Morphological and Electrical Characterization of Solution Processable Low Bandgap Organic Materials

Abstract

The objectives of this research was to develop the chemistry for the synthesis of a new class of pentacene and tetracene containing polymers and oligomers. These materials were designed to have low bandgap and high charge carrier mobility. The general synthetic routes were developed for this class of materials. The synthesized new molecules and polymers were used for structural property relation studies to understand the effect of molecular structure on solid state packing, energy level and absorption. New molecular design rules were found for high performance electron transporting materials. A general correlation between charge carrier type and the molecular orbital energy levels was obtained for the first time using the large number of compounds synthesized.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Dec 05, 2008
Accession Number
ADA494817

Entities

People

  • Zhenan Bao

Organizations

  • Stanford University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Carbon Nanotubes
  • Charge Carriers
  • Chemistry
  • Crystal Structure
  • Crystals
  • Electrons
  • Energy Bands
  • Energy Levels
  • Field Effect Transistors
  • Materials
  • Materials Science
  • Mobility
  • Molecules
  • Organic Materials
  • Semiconductors
  • Solar Cells
  • Thin Film Transistors

Fields of Study

  • Chemistry
  • Materials science

Readers

  • Polymer Science and Engineering.
  • Quantum Chemistry
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics
  • Space