Oxidation of Polyethylene: A Comparison of Plasma and Ultraviolet Ozone Processing Techniques

Abstract

Plasma and ultraviolet (UV) ozone treatments were compared as methods to functionalize ultrahigh molecular weight polyethylene films in order to make them more compatible with materials or reactive for subsequent surface chemistry. Oxidation states and atomic compositions were determined using x-ray photoelectron spectroscopy, while surface energy and bond stability were probed with contact angle goniometry. Both modification techniques increased the surface energy of the polymer, and the bonds formed were found to be stable over a period of 30 days. Plasma treatment times were much shorter than UV ozone; thus, plasma was determined to be a more efficient surface modification technique.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2009
Accession Number
ADA494867

Entities

People

  • Ben Stein
  • Daphne Pappas
  • Nicole E. Zander

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • C4I
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Carboxylic Acids
  • Chemical Reactions
  • Chemistry
  • Corrosion Resistance
  • Dielectric Polymers
  • Energy
  • Equations
  • Films
  • High Resolution
  • Materials
  • Measurement
  • Oxidation
  • Polymers
  • Surface Chemistry
  • Surface Energy
  • X Ray Photoelectron Spectroscopy
  • X Rays

Readers

  • Surface Coatings Technology.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene