Quantitative Study of the Effects of Chemical Additives in Propellant Flames

Abstract

This research addresses perceived needs of the U.S. Army in the development and use of biodiesel fuels and in the combustion chemistry of small cyclic nitramines. Studies are described of the chemistry of simple methyl and ethyl esters chosen as surrogates for the long chain mono-alkyl esters that are primary constituents of biodiesel fuels. The principal goal of these studies is the elucidation of the reaction mechanisms responsible for observed reductions in particulates, polycyclic aromatics, carbon monoxide, and unburned hydrocarbons when biodiesel is introduced as an additive to petroleum diesel. A recent research initiative is the study of the flame chemistry of morpholine, a simple cyclic nitramine, distantly related to the complex nitramine propellants HMX and RDX.

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Document Details

Document Type
Technical Report
Publication Date
Nov 02, 2008
Accession Number
ADA498523

Entities

People

  • Terrill A. Cool

Organizations

  • Cornell University

Tags

Communities of Interest

  • C4I
  • Human Systems

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Cyclic Hydrocarbons
  • Diesel Fuels
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Ionization
  • Mass Spectrometry
  • Measurement
  • Organic Chemistry
  • Reaction Mechanisms
  • Spectrometry

Fields of Study

  • Chemistry

Readers

  • Agricultural Chemistry/Soil Science
  • Organic Chemistry
  • Petroleum Engineering