Capture of Organic Vapors Using Adsorption and Electrothermal Regeneration

Abstract

Activated-carbon-fiber cloth (ACFC) is an alternative adsorbent to granular activated carbon (GAC) for removing and recovering organic vapors from gas streams. Electrothermal desorption (ED) of ACFC provides rapid regeneration while requiring less energy compared to traditional regeneration techniques used with GAC. This paper provides proof-of-concept results from a bench-scale ACFC adsorption system. The automated system captured 1,000 ppmv of hazardous air pollutants/volatile organic compounds (HAPs/ VOCs) from air streams and demonstrated the use of ED, using ac voltage, to recover the HAP/VOC as a pure liquid. The desorbed HAP/VOC condensed onto the inner walls of the adsorber and was collected at the bottom of the vessel, without the use of ancillary cooling. Seventy percent of the HAP/VOC was collected per cycle as condensate, with the balance being retained in the regenerated adsorber or recycled to the second adsorber. ED with in-vessel condensation results in minimal N2 consumption and short regeneration cycle times allowing the process to be cost competitive with conventional GAC-based adsorption processes. This technology extends the application of carbon adsorption systems to situations that were previously economically and physically impractical.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 2004
Accession Number
ADA498875

Entities

People

  • K. J. Hay
  • Katherine D. Dombrowski
  • M. Asce
  • Mark J. Rood
  • Patrick D. Sullivan

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Adsorption
  • Air Force Research Laboratories
  • Air Pollutants
  • Air Pollution
  • Alkanes
  • Carbon Fibers
  • Chemistry
  • Chlorides
  • Cost Estimates
  • Engineering
  • Environmental Engineering
  • Environmental Protection
  • Flow Rate
  • Gas Flow
  • Organic Compounds
  • Vapor Pressure
  • Volatile Organic Compounds

Fields of Study

  • Environmental science

Readers

  • Aquatic Ecology
  • Environmental Engineering.
  • Internal Combustion Engine (ICE) Technology.