Organic Vapor Recovery and Energy Efficiency During Electric Regeneration of an Activated Carbon Fiber Cloth Adsorber

Abstract

An electrothermal-swing adsorption system was demonstrated on the bench scale for capture and recovery of organic vapors from air streams. Methyl propyl ketone (MPK), methyl ethyl ketone, n-hexane, acetone, and methylene chloride were removed and recovered at 200-1,020 ppm(v) in a 40.0 slpm air stream while using activated carbon fiber cloth (ACFC) adsorbent. Removal efficiencies were greater than 99.9%. Liquid recovery fractions increased with increasing relative pressure, ranging from 0.11 for methylene chloride (P/P(sat)=2.1X10(exp -3)) to greater than 0.80 for MPK (P/P(sat)=2.2X10(exp -2)). The electrical energy consumed during regeneration per mol of liquid organic compound recovered decreased with increasing relative pressure of the inlet gas stream, ranging from 4,698 kJ/mol for methylene chloride to 327 kJ/mol for MPK. Equilibrium ACFC adsorption capacity, throughput ratio, and length of unused bed were also evaluated. These results are encouraging for the development of a new technology to capture and readily recover a wide range of organic vapors from air streams.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 2004
Accession Number
ADA498918

Entities

People

  • A. M. Asce
  • Christopher M. Lehmann
  • David Ramírez
  • K. J. Hay
  • Katherine D. Dombrowski
  • M. Asce
  • Mark J. Rood
  • Patrick D. Sullivan

Organizations

  • University of Illinois Urbana–Champaign

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Carbon Fibers
  • Chemistry
  • Chlorides
  • Desorption
  • Efficiency
  • Energy Efficiency
  • Engineering
  • Environmental Engineering
  • Environmental Protection
  • Fibers
  • Greenhouse Effect
  • Mass Transfer
  • New York
  • Organic Compounds
  • Vapor Pressure
  • Volatile Organic Compounds

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Aquatic Ecology
  • Organic Chemistry