Diagnostic and Therapeutic Radiopharmaceutical Agents for Selective Discrimination of Prostate Cancer

Abstract

The project investigated the development of ligand linked Flutamide analogs for complexing a M(CO)3 (Re,99mTc) organometallic species to target prostate cancer for imaging and therapy. The project has been successful in developing and testing new synthetic strategies for this application. General methods were established for preparing the complexes in excellent yields(>95%) at (10-4,10-5 M) ligand concentration, testing the stability of the complexes (pH, temperature) and in vitro (serum, AR +/- prostate cancer cells). First generation 99mTc flutamide analogs were examined. The results indicated the complexes formed with tridentate ligands (i.e., cysteine, histidine) were successfully prepared and maintained stability. The "2+1" approach analogs were prepared, however, failed to maintain the complex conformation, when examined under biological conditions. Second generation and addition coordination modes are also being investigated.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 2008
Accession Number
ADA499840

Entities

People

  • Paul D Benny

Organizations

  • Washington State University

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Amino Acids
  • Androgen Receptors
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Coordination Complexes
  • Detectors
  • Health Services
  • Inorganic Chemistry
  • Liquid Chromatography
  • Medical Personnel
  • Organic Chemistry
  • Prostate Cancer
  • Therapy
  • Three Dimensional

Fields of Study

  • Chemistry

Readers

  • Agricultural Chemistry/Soil Science
  • Medical Imaging.
  • Molecular and Cellular Biochemistry