Characterization of Near Wall Surface Chemistry and Fluid Interaction in Hypersonic Boundary Layers

Abstract

We have demonstrated the importance of the O + N surface reaction for catalytic atom recombination in dissociated nitrogen oxygen mixtures. This was accomplished using numerical and experimental studies in a tube side arm reactor, a microwave discharge to generate atomic nitrogen and an NO titration technique to generate different mixtures of O and N atoms. In the first approach, two photon LIF of atomic oxygen and atomic nitrogen were used to show how the relative atom concentration varied with position along the diffusion tube as a function of O/N ratio at the diffusion tube inlet. The experimental and numerical results confirmed and extended earlier experiments. In the second approach, single photon LIF was used together with isotropically labeled titration gases to detect surface produced NO directly at two different positions in the diffusion tube as a function of O/N ratio at the diffusion tube inlet.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 2009
Accession Number
ADA501209

Entities

People

  • Dusan Pejakovic
  • Jochen Marschall
  • Lian Duan
  • M. Pino Martı́n

Organizations

  • Princeton University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Boundary Layer
  • Chemical Reactions
  • Chemistry
  • Computational Fluid Dynamics
  • Dye Lasers
  • Fluid Dynamics
  • Heat Transfer
  • Ideal Gas Law
  • Laser Beams
  • Laser Dyes
  • Laser Induced Fluorescence
  • Measurement
  • Molecular Physics
  • Physical Chemistry
  • Physics Laboratories
  • Surface Chemistry
  • Surface Reactions

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Organic Chemistry
  • Plasma Physics.

Technology Areas

  • Hypersonics
  • Hypersonics - Hypersonic Flight