Liquid Metal Anode for JP-8 Fuel Cell

Abstract

Report developed under STTR contract W911NF-08-C-0075 for topic A08-T007. JP-8 is a high-energy density liquid fuel available to the soldier, but its electrochemical oxidation in a fuel cell is problematic. The purpose of this effort is to advance the development of a liquid metal based fuel cell operating directly on JP-8 for application in a field portable battery charger. During Phase 1 an evaluation was performed of a range of liquid metal anodes capable of oxidizing JP-8, including several p-orbital metals. Liquid tin selected as the only anode material that has demonstrated sustainable electrochemical oxidation of JP-8. The relevant physio-chemical governing parameters were defined for fuel oxidation by liquid tin. One-dimensional steady state and transient simulation models of the fuel cell were created. The models identified optimization pathways including reduced cathode polarization and lower electrolyte polarization. Finally, a conceptual design was developed for a complete 500 watt battery charger operating on JP-8. Based on mission needs analysis, a systems requirement matrix was developed. Systems engineering tasks included a system level thermodynamic analysis and development of conceptual drawings of the overall system. Suggested tasks for Phase 2 include the construction of a direct JP-8 stack for testing and demonstration.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jan 15, 2009
Accession Number
ADA501657

Entities

People

  • Ralph White
  • Stephen Klotz
  • Thomas Tao

Tags

Communities of Interest

  • Energy and Power Technologies
  • Engineered Resilient Systems
  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Battery Chargers
  • Catalysis
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Energy
  • Exhaust Gases
  • Fuel Cells
  • Fuel Efficiency
  • Liquids
  • Logistics
  • Materials Processing
  • Power Supplies
  • Solid Oxide Fuel Cells
  • Storage Batteries
  • Turbines

Readers

  • Battery Technology and Engineering
  • Combustion science or combustion engineering.
  • Joint Military Operations and Doctrine.

Technology Areas

  • Biotechnology
  • Space
  • Space - Hall-Effect Thruster