Accuracy Analysis for Kinetic Modeling of Homogeneous Condensation in Plumes

Abstract

Two different approaches for modeling the clustering in rapidly expanding plumes have been reported in the literature. The first approach, known as the classical approach, takes its starting point from the classical nucleation theory (CNT) which is based on equilibrium thermodynamics. The second one, known as the kinetic approach, treats nucleation as the process of kinetic chemical aggregation. The first, macroscopic, approach, while being useful and found to be applicable for a number of flow scenarios, has at the same time a number of drawbacks that are very difficult to overcome. In many cases when CNT-based results cannot be fitted to experimental data. For example, the CNT-based prediction of the cluster size distributions significantly deviated from experimental data. This is also consistent with the work of Ref. 6, where it was also found that the correct prediction of the cluster size distribution along with the internal and translational energy distributions is beyond the area of applicability of the classical approach.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2009
Accession Number
ADA502920

Entities

People

  • Deborah Ann Levin
  • Ingrid Wysong
  • Michael Zeifman
  • Ryan Jansen
  • Sergey F. Gimelshein
  • Zheng Li

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force Research Laboratories
  • Computational Fluid Dynamics
  • Energy
  • Energy Transfer
  • Experimental Data
  • Fluid Dynamics
  • Gas Dynamics
  • Heat Capacity
  • Heat Energy
  • Mathematical Models
  • Molecular Dynamics
  • Monte Carlo Method
  • Nucleation
  • Numerical Analysis
  • Rarefied Gas Dynamics
  • Simulations
  • Thermodynamics

Fields of Study

  • Chemistry

Readers

  • Combustion and Flow Dynamics.
  • Materials Science and Engineering.
  • Nanocomposite Materials Science