Research Synthesis and Characterization of 2D Conjugated Polymers

Abstract

Use heterocyclic multidentate monomers specifically designed for this purpose by Density Functional Theory calculations. The main challenge in this design is the geometry of the monomer and the resulting oligomer (i.e., the most favorable all-trans geometry of a polythiophene chain on the Scheme should necessarily result in a continuous brick wall 2D structure). Furthermore, the design should eliminate any steric hindrances in the oligomers which would result in non-planar conformations.

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Document Details

Document Type
Technical Report
Publication Date
Jul 13, 2007
Accession Number
ADA504213

Entities

People

  • Fredrico Rosei

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Conductive Polymers
  • Conjugated Polymers
  • Contracts
  • Density Functional Theory
  • Electron Beams
  • High Vacuum
  • Infrared Spectroscopy
  • Macromolecules
  • Materials
  • Molecules
  • Monitoring
  • Oligomers
  • Peak Power
  • Polymerization
  • Polymers
  • Spectroscopy
  • X Ray Photoelectron Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Computational Fluid Dynamics (CFD)
  • Polymer Science and Technology
  • Systems Analysis and Design