Molecular Dynamics Simulation of the Kinetic Reaction of Ni and Al Nanoparticles

Abstract

The U.S. Army has an interest in the use of alloys that produce excessive heat during formation and can be used for structural purposes such as shell casings. Molecular dynamics simulations have been used to provide a more thorough understanding of one of these alloys systems, namely the kinetic reaction of Ni and Al nanoparticles. We have considered the affect of primary particle size on sintering time and sintering temperature for separate nanoparticles and for coated nanoparticles in the form of Ni-coated Al nanoparticles and Al-coated Ni. Simulation results show that the sintering time for coated nanoparticles is linearly dependent upon the number of atoms or volume of the sintering nanoparticles. We have also found that nanoparticle size and surface energy is an important factor in determining the adiabatic reaction temperature.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 2008
Accession Number
ADA505703

Entities

People

  • B. J. Henz
  • M. R. Zachariah
  • T. Hawa

Organizations

  • United States Army Research Laboratory

Tags

DTIC Thesaurus Topics

  • Chemistry
  • Computer Simulations
  • Dynamics
  • Energy
  • Heat Energy
  • Heat Of Formation
  • Materials
  • Materials Science
  • Mathematical Models
  • Mechanical Properties
  • Molecular Dynamics
  • Nanoparticles
  • Particle Size
  • Particles
  • Physical Properties
  • Simulations
  • Surface Energy

Fields of Study

  • Materials science

Readers

  • Combustion science or combustion engineering.
  • Materials Science and Engineering.
  • Nanocomposite Materials Science

Technology Areas

  • Biotechnology