Environmentally Friendly Bio-Based Vinyl Ester Resins for Military Composite Structures

Abstract

Liquid resins used for molding composite structures a significant source of volatile organic compounds (VOC) and hazardous air pollutant (HAP) emissions. One method of reducing styrene emissions from vinyl ester (VE) resins is to replace some or all of the styrene with fatty acid-based monomers. These fatty acid vinyl ester resins allow for the formulation of high performance composite resins with no more than 25 wt% styrene. As a result, these resins are currently being demonstrated/validated for DoD use on Army tactical vehicles, including HMMWV hoods, HMMWV helmet hardtops, T-38 dorsal covers, and composite rudders for the Navy. Composite panel validation studies have been performed, showing that the fatty acid-based resins have sufficient, modulus, strength, glass transition temperature, and resistance to weathering. Demonstration parts have been prepared and are in the process of being validated for military use.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 2008
Accession Number
ADA505758

Entities

People

  • Alexander Grous
  • Dane Morgan
  • David Fudge
  • Frank Bruce
  • Giuseppe R Palmese
  • Ian Mcaninch
  • James M. Sands
  • John Gillespie Jr.
  • John J. la Scala
  • Jorge Gomez
  • Ken Patterson
  • Lawrence Coulter
  • M. Starks
  • Maureen Foley
  • Roger Crane
  • Stephen Andersen
  • Steven E. Boyd
  • Xing Geng

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Biomedical
  • Ground and Sea Platforms
  • Human Systems

DTIC Thesaurus Topics

  • Alkenes
  • Chemistry
  • Composite Material Fabrication
  • Composite Materials
  • Composite Structures
  • Fatty Acids
  • Glass Transition Temperature
  • Material Degradation Processes
  • Materials
  • Materials Processing
  • Materials Science
  • Mechanical Properties
  • Mechanical Working
  • Modulus Of Elasticity
  • Polymer Matrix Composites
  • Transition Temperature
  • Volatile Organic Compounds

Fields of Study

  • Materials science

Readers

  • Internal Combustion Engine (ICE) Technology.
  • Polymer Science and Engineering.
  • Surface Coatings Technology.