N-Chloramide Modified Nomex(Registered) as a Regenerable Self-Decontaminating Material for Protection Against Chemical Warfare Agents (Postprint)

Abstract

Recent interest in the treatment of textiles for chemical and biological agent defense has led to the creation of materials that contain N-chloramide moieties. These materials have demonstrated efficacy against weaponizable bacteria, mustard, and VX, as well as possessing antimicrobial properties against nuisance organisms that cause conditions such as athlete's foot or molds. Here, N-chloramides have been attached to Nomex intended for use as self-decontaminating regenerable military textiles. The materials were assayed for content of active oxidizing agent, and tested for efficacy against 2-chloroethyl ethyl sulfide and Demeton-S, simulants for mustard and VX, respectively. The decomposition products for each reaction were identified as well as reaction pathways to form each by-product as correlated to analogous products of mustard and VX. Furthermore, the rate constant for the neutralization of each simulant on the reactive material was calculated from data collected by GC-MS and ATR-FTIR real-time studies.

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Document Details

Document Type
Technical Report
Publication Date
Feb 26, 2009
Accession Number
ADA506668

Entities

People

  • Eileen T. Shannon
  • Jeffery R. Owens
  • Rashelle S. Mcdonald
  • Ryan A. Hayn
  • Wallace B. Salter

Organizations

  • Applied Research Associates (United States)

Tags

Communities of Interest

  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Chemical Synthesis
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Chemistry
  • Composite Materials
  • Electronic Mail
  • Ethers
  • Hypochlorous Acid
  • Laminates
  • Mass Spectrometry
  • Mustard Agents
  • Nerve Agents
  • Phosgene
  • Polymers

Readers

  • Analytical Chemistry
  • Neurotoxicology
  • Surface Coatings Technology.