Performance Enhancement of Large Area Solar Cells by Incorporating Nanophosphors: A ZnOS Demonstrator Solar Cell and Its Efficiency

Abstract

High quality ternary ZnO1-xSx (0<=x<=0) nanocrystals in the whole composition range were synthesized for the first time by chemical method. The composition dependence (0<=x<=0) of band gap, multi-phonon resonant Raman scattering and photoluminescence studies were carried out in detail. The energy band gaps of these ternary ZnO1-xSx(0<=x<=0) nanocrystals show strong bandgap bowing of 3.7 eV. The photoluminescence efficiency of the ternary nanocrystals is demonstrated in its use for enhancement of photovoltaic cell efficiency. Preliminary results demonstrate a 3% enhancement in the efficiency of ZnOS Demonstrator Solar Cell. To enhance the efficiency further, it is recommended 1) to improve the x values of down-conversion of the ZnO1-xSx (0<=x<=0) layers and luminescence activator center and 2) to improve the interface between nanophosphors of Si solar cells, as well as optimizing the thickness (in mm) to absorb and down conversion efficiently.

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Document Details

Document Type
Technical Report
Publication Date
Dec 16, 2009
Accession Number
ADA512649

Entities

People

  • Rameshwar N. Bhargava

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Band Gaps
  • Cells
  • Coatings
  • Conversion
  • Efficiency
  • Electromagnetic Spectra
  • Energy
  • Energy Bands
  • Nanocrystals
  • Photoluminescence
  • Radiation
  • Raman Scattering
  • Scattering
  • Solar Cells
  • Solar Panels
  • Solar Spectrum
  • Spectra

Fields of Study

  • Materials science

Readers

  • Astronomy/Astrophysics
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Semiconductor Device Technology