Ink-Jet Printing: A Versatile Method for Multilayer Solid Oxide Fuel Cells Fabrication (Postprint)

Abstract

The potential of ink-jet printing for fabrication of components for solid oxide fuel cells has been explored. An anode interlayer, consisting of a composite of NiO and yttria-stabilized zirconia (YSZ), and an electrolyte layer, YSZ (8 mol%), were ink-jet printed on a tape cast anode support, 55 wt% NiO-45 wt% YSZ (8 mol%). Scanning electron microscopy of the printed layers sintered at 1400 deg C revealed a dense electrolyte layer measuring 10-12 microns in thickness. Single cells using these printed layers and strontium-doped lanthanum manganate (LSM, La0.8Sr0.2MnO3)-based pasted cathodes were assessed by DC polarization and AC complex impedance methods. The cells exhibited a stable open circuit voltage of 1.1 V around 800 deg C, in a hydrogen atmosphere. A maximum power density of 500 mW/sq cm was achieved at 850 deg C for a typical cell with the electrolyte and anode interlayer cosintered at 1400 deg C. A composite cathode interlayer, LSM-YSZ, and a cathode current collection layer, LSM, were also ink-jet printed and incorporated in single cells. However, cells with all components ink-jet printed showed decreased performance. This pointed to critical issues in the composite cathode microstructure, which is controlled by the composite ink design/formulation and printing parameters that need to be addressed.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 2010
Accession Number
ADA515597

Entities

People

  • Mary A. Sukeshini
  • Ryan Cummins
  • Ryan M. Miller
  • Thomas L. Reitz

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Ceramic Materials
  • Composite Materials
  • Electron Microscopy
  • Fabrication
  • Fuel Cells
  • Impedance
  • Materials
  • Materials Engineering
  • Materials Processing
  • Materials Science
  • Microscopy
  • Microstructure
  • Scanning Electron Microscopy
  • Solid Oxide Fuel Cells
  • Thin Films

Fields of Study

  • Materials science

Readers

  • Electrical Engineering
  • Nanofabrication and Microfabrication.
  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Biotechnology
  • Microelectronics
  • Microelectronics - Graphene