Physical and Chemical Processes in Flames

Abstract

The scope of the present program covers the structure and response of laminar and turbulent premixed and diffusion flames, with emphases on effects of high pressure, flame/flow unsteadiness, and chemistry. Studies on combustion chemistry included: (1) experimental determination of stretch-affected ignition and extinction limits of premixed and nonpremixed flames and the laminar flame speeds for various fuel-oxidizers including CO/H2, ethylene, 1,3-butadiene, n-heptane, and methyl decanoate; (2) further advances on the method of directed relation graph for mechanism reduction, and auxiliary methodologies for facilitated computation including analytic solution of the quasi-steady species, the lumping of diffusion coefficients, and the development of a fitting formula for the falloff curves of unimolecular reactions; and (3) soot formation in flames through mapping of the toluene flame structure and direct numerical simulations of the turbulent premixed and diffusion flame structure. Studies on flame dynamics show strong coupling between intrinsic flamefront pulsating instability, radiation heat loss, flame stretch, and the extinction limits for diffusion flames, with and without forcing. These accomplishments are expected to be useful to the general interests of AFOSR in the fundamental and practical issues of flame dynamics, chemical kinetics, turbulent combustion, soot formation, radiative hear transfer, flame extinction, and stabilization.

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Document Details

Document Type
Technical Report
Publication Date
Feb 15, 2010
Accession Number
ADA519476

Entities

People

  • Chung K. Law

Organizations

  • Princeton University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Computations
  • Diffusion Coefficient
  • Ethylenes
  • High Pressure
  • High Temperature
  • Hydrocarbons
  • Ignition
  • Ignition Lag
  • Oxidation
  • Pyrolysis
  • Steady State

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.