Laboratory Studies and Preliminary Evaluation of Destructive Technologies for the Removal of RDX from the Water Waste Stream of Holston Army Ammunition Plan

Abstract

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) is the primary constituent in the explosive munitions that are produced at Holston Army Ammunition Plant (HSAAP), Kingsport, TN. Part of a modernization effort for the 66-year-old plant includes the goal of zero RDX discharge to the facility industrial wastewater treatment plant. This study examines multiple technologies for removing RDX from the process waste stream at Holston Army Ammunition Plant. The treatment technologies evaluated included granular activated carbon (GAC), anoxic biotreatment, zerovalent iron (ZVI), alkaline hydrolysis, ultra-violet oxidation, and electrochemical decomposition. Evaluation criteria include capital and operating cost, and effectiveness in transforming RDX to nontoxic end products. Based on laboratory assessments using site water, alkaline hydrolysis and electrochemical treatment were selected for pilot scale evaluation. The RDX removal half-lives for the selected technologies were on the order of 0.25 hr with decomposition of RDX from 10,000 micrograms/L to less than 20 micrograms/L.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 2010
Accession Number
ADA522315

Entities

People

  • David B. Gent
  • Deborah R. Felt
  • Greg O'connor
  • Jared L. Johnson
  • Steven L. Larson

Organizations

  • Engineer Research and Development Center

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Ammunition
  • Buffers (Chemistry)
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Decomposition
  • Disruptive Technology
  • Ecology
  • Environmental Protection
  • Explosives
  • Groundwater
  • Liquid Chromatography
  • Mass Transfer
  • Materials
  • Materials Laboratories
  • Munitions
  • Rdx

Fields of Study

  • Environmental science

Readers

  • Agricultural Chemistry/Soil Science
  • Groundwater Contamination Remediation.