Decontamination Efficacy of Candidate Nanocrystalline Sorbents with Comparison to SDS A-200 Sorbent: Reactivity and Chemical Agent Resistant Coating Panel Testing

Abstract

Several nanocrystalline reactive sorbents, of varied particle size and surface area, were examined as decontaminating sorbents. The reaction kinetics of VX. GD, and HD were determined in addition to efficacy for surface decontamination of Chemical Agent Resistant Coating (CARC) paint. The Sorbent Decon System (SDS) A-200 sorbent was utilized as a control. The best sorbent for VX was nTi02, which enabled a half-life of <2 min. Comparable half-lives for GD (tens-of minutes) were observed on nTi02, nMgO, and the commercial FAST-ACT" sorbent. Half-lives of a few to many hours were observed for HD on nAl:Ot, nTiO:, FAST-ACT*, and A-200. but only with sufficient surface hydration. Regarding reactivity only, A-200 did not perform as well as the nanocrystalline sorbents, especially for VX and GD. However, all of the sorbents. A-200 included, provided for the comparable removal of HD and GD from CARC panels, ca. 75 and 87%, respectively. An apparent surface-porosity of 0.8 cc/m" for the CARC paint is presumed responsible for this low efficacy. Smaller sorbent particle sizes (<5 uM) did not increase surface decontamination efficacy.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 2010
Accession Number
ADA533064

Entities

People

  • George Wayne Wagner

Organizations

  • Edgewood Chemical Biological Center

Tags

Communities of Interest

  • Counter WMD

DTIC Thesaurus Topics

  • Aluminum Oxides
  • Chemical Kinetics
  • Chemical Synthesis
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemical Weapons
  • Chemistry
  • Decontamination
  • Dwell Time
  • Hydration
  • Kinetics
  • Magnesium Compounds
  • Materials
  • Metal Oxides
  • Particle Size
  • Particles
  • Plastic Explosives

Readers

  • Environmental Engineering.
  • Neurotoxicology
  • Surface Coatings Technology.