Cathodoluminescence of Irradiated Hafnium Dioxide

Abstract

The purpose of this research is to understand the effect of radiation on HfO2 thin films, and to compare the quality of HfO2 thin films produced by both atomic layer deposition (ALD) and pulsed laser deposition (PLD); PLD samples had varying substrate temperatures during deposition (300 deg C, 500 deg C, and 750 deg C). The entirety of this research was conducted using cathodoluminescence (CL) as the examination method. The excitation source was a Kimball Physics EMG-12 electron gun. The photomultiplier tube contained a gallium arsenide photocathode. Measurements were made with beam energies ranging from 1 to 10 keV and beam currents ranging from 30 to 50 microA, both at room temperature and at 7K. The experimentally-determined band gap of HfO2 was consistent with published data, but many other features found in the literature were not present in the CL data obtained. HfO2 appeared to be radiation hard up to the levels of radiation to which it was exposed. A higher substrate temperature during deposition for PLD samples produced a better material than lower temperatures. ALD produced a more consistent thickness but PLD ultimately produced a better quality material with respect to the spectrum obtained.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 2011
Accession Number
ADA538491

Entities

People

  • Emily A. Purcell

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Beta Particles
  • Charged Particles
  • Chemical Vapor Deposition
  • Crystal Structure
  • Diffraction
  • Electrons
  • Energy Bands
  • Gamma Rays
  • Ionization
  • Ionizing Radiation
  • Light Sources
  • Materials
  • Optical Properties
  • Scattering
  • Solid State Physics
  • Spectra

Fields of Study

  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Semiconductor Device Technology
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene