Thermal Stability of Milled Nanocrystalline Tungsten Powders

Abstract

The development of nanocrystalline and ultrafine-grained bulk materials through powder metallurgy processes has long been constrained by the thermal stability of nanostructures. Many difficulties arise due to the fact that grain growth and densification occur within the same temperature regime. Additionally, the mechanisms supporting densification require some degree of grain coarsening in order to achieve full density. This study outlines the development of a thermally stable nanocrystalline tungsten powder and discusses the influence of grain size stability on the overall densification rate during pressureless sintering in hydrogen atmosphere. Furthermore, the activation energy of sintering is calculated to determine whether the mechanisms of grain growth and densification can be decoupled through the addition of thermal grain stabilizers.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 2011
Accession Number
ADA543111

Entities

People

  • Brady Butler
  • Eric Klier
  • Matt Kelly
  • Micah Gallagher

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Bulk Materials
  • Chemical Compounds
  • Chemistry
  • Diffraction
  • Electron Microscopy
  • Energy
  • Grain Growth
  • Grain Size
  • Heat Of Activation
  • Materials
  • Materials Processing
  • Nanostructures
  • Particle Size
  • Particles
  • Powder Metallurgy
  • Powders
  • Thermal Stability

Fields of Study

  • Materials science

Readers

  • Control Systems Engineering.
  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Microelectronics