Extraction of Carbon Dioxide from Seawater by an Electrochemical Acidification Cell. Part 2 - Laboratory Scaling Studies

Abstract

An electrochemical acidification cell has been developed to extract large quantities of carbon dioxide fast and efficiently from seawater. Verification and validation of the electrochemical cell as a function of increased operational time and flow rate using Key West seawater is reported. The electrolytic regeneration of cation exchange resin allowed simultaneous and continuous ion exchange and regeneration to occur within the cell along with control of the seawater pH. At pHs of less than 6.0, carbon dioxide in the seawater was readily removed by vacuum degassing. At higher seawater flow rates, the flow rate to current ratio for a given pH was significantly improved. Prolonged operation of the cell caused the electrical resistance within the cell to increase by 34% signifying scaling on the cathode. These results are significant to the future design of this technology as it is scaled and transitioned to a marine environment.

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Document Details

Document Type
Technical Report
Publication Date
Apr 11, 2011
Accession Number
ADA544072

Entities

People

  • Dennis R. Hardy
  • Felice Dimascio
  • Frederic W. Williams
  • Heather Willauer
  • M. K. Lewis

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkenes
  • Carbon Dioxide
  • Chemical Synthesis
  • Chemistry
  • Efficiency
  • Electrical Resistance
  • Electrochemical Cells
  • Electrodes
  • Feasibility Studies
  • Flow Rate
  • Fuels
  • Hydrocarbon Fuels
  • Ion Exchange
  • Jet Engine Fuels
  • Materials
  • Military Research
  • Resistance

Fields of Study

  • Chemistry

Readers

  • Environmental Engineering
  • Surface Engineering/Surface Coating Technology.