Production of Dioxins and Furans from the Burning of Excess Gun Propellant

Abstract

The burning of bags of excess gun propellant left over after an artillery exercise is a common practice on Canadian Forces Base (CFB) ranges and training areas. This process is carried out by aligning and burning the bags on the ground. This operation is known to leave significant quantities of energetic residues. It was also suspected of producing, among its combustion products, dioxins and furans, two structurally and chemically related chlorinated compounds known to be toxic and persistent in the environment. At CFB Petawawa, dioxins and furans were detected in some soil and water samples. The work reported here was aimed at studying the potential production of dioxins and furans from the combustion of gun propellants using a flare as an igniter. The results indicated that this production was not related to the combustion pattern, chemical composition or mass of the gun propellant, but to the presence of the igniter. The accepted procedure published by the Canadian Forces requires the use of a railroad fusee or a flare (like the warning flares used on roads at night) as the ignition source for the gun propellant. This trial should be replicated, and if further trials confirm that the railroad fusee is the source of the dioxins and furans, the disposal procedure for excess gun propellant by open burning should be modified.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2011
Accession Number
ADA545079

Entities

People

  • Isabelle Poulin
  • Sonia Thiboutot
  • Sylvie Brochu

Organizations

  • DRDC Valcartier

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Composition
  • Combustion
  • Combustion Products
  • Energetic Materials
  • Environment
  • Environmental Protection
  • Groundwater
  • Gun Propellants
  • Mass Spectrometry
  • Materials
  • Materials Laboratories
  • National Security
  • Organic Materials
  • Propellants
  • Propelling Charges
  • Security
  • Training

Readers

  • Aquatic Ecology
  • Combustion science or combustion engineering.