Synthesis of FeSb2 Nanorods and Nanoparticles by Solvothermal Synthesis Routes (Briefing Charts)

Abstract

FeSb2 has recently been considered as a novel thermoelectric material due to a Seebeck coefficient of ~-45000 microVK-1 and a thermoelectric power factor of ~2300 microWK-2/cm at low temperatures. However, its thermoelectric potential is limited by a high thermal conductivity. To lower the thermal conductivity, both nanorods and nanoparticles of FeSb2 were synthesized. Nanorods were synthesized following a previously published solvothermal synthesis in ethanol. Nanoparticles were synthesized using a novel sodium naphthalenide reduction in triglyme at ambient pressure. XRD was used to characterize both materials.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2010
Accession Number
ADA546398

Entities

People

  • Douglas Dudis
  • Harry Seibel
  • Joel E. Schmidt

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Air Force Research Laboratories
  • Coefficients
  • Conductivity
  • Heat Energy
  • High Temperature
  • Low Temperature
  • Materials
  • Military Research
  • Nanoparticles
  • Nanostructures
  • Particle Size
  • Particles
  • Thermal Conductivity
  • Transport Properties
  • United States

Fields of Study

  • Materials science

Readers

  • Nanofabrication and Microfabrication.
  • Organic Chemistry
  • Solar Photovoltaics and Thermoelectric Devices.

Technology Areas

  • Biotechnology