Carbon-Coated Current Collectors for High-Power Lithium-Ion Secondary Batteries

Abstract

The goal of this project is to develop a viable C-coating process of the current collector in order to improve the overall power performance of the electrode of Li-ion batteries. Two major parts of research works toward this goal were carried out. (1) Al and Cu foils were subjected to high-temperature chemical vapor deposition (T-CVD) to produce surface C-coating, and the resulting foils were used as current collectors for LiFePO4 and Li4Ti5O12. The C-coating remarkably enhanced the power performance of both electrodes. The enhancement was attributed to a combination of two factors--removal of the native oxide layer and modification of surface hydrophobicity--both of which reduced the resistance at the current-collector/ active layer interface. (2) A low-temperature plasma-assisted chemical vapor deposition (PA-CVD) vacuum chamber was built and tested. The design of the chamber allows for roll-to-roll plasma treatment of metal foils under vacuum condition, and it is ready for carry out low-temperature coating processes in the next-year phase of research.

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Document Details

Document Type
Technical Report
Publication Date
Sep 20, 2011
Accession Number
ADA550134

Entities

People

  • Nae-lih Wu

Organizations

  • National Taiwan University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Accumulators
  • Chambers
  • Charge Transfer
  • Chemical Vapor Deposition
  • Chemistry
  • Coatings
  • High Temperature
  • Hydrophobic Properties
  • Lithium Ion Batteries
  • Low Temperature
  • Materials
  • Resistance
  • Spectra
  • Storage Batteries
  • Supercapacitors
  • Vacuum Chambers
  • Vapor Deposition

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Pulsed Power and Plasma Physics.
  • Solar Photovoltaics and Thermoelectric Devices.