Fluorescence Properties of Fe2+- and Co2+-doped Hosts of CdMnTe Compositions as Potential Mid-Infrared Laser Materials

Abstract

Solid-state laser sources emitting in a mid-infrared (IR) spectral range are of significant practical interest due to the great variety of potential applications in the biomedical industry, remote sensing, pollution monitoring, molecular spectroscopy, residual gas tracing, and IR countermeasures. The need for mid-IR wavelengths directly obtainable from a diode-pumped solid-state gain medium stimulates searches for new laser materials with wide tunability. We report the results of spectroscopic investigation of Fe(2+)- and Co(2+)-doped low-phonon single crystals of the cadmium telluride (CdTe) family. It is shown that compositional changes of the host material significantly affect the radiative lifetime of the initial laser level, the bandwidth of the emission and absorption spectra, and their overall positioning, which will translate into potential mid-IR laser threshold and tunability. Single crystal composition also affects the Co(2+) and Fe(2+) dopant lifetimes and temperature dependencies. Crystal growth effort is underway in order to improve the quality of the samples toward satisfying laser-grade loss figure requirements.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 2011
Accession Number
ADA553046

Entities

People

  • Mark Dubinskii
  • Sudhir Trivedi
  • Tigran Sanamyan

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical
  • Sensors

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Chemical Vapor Deposition
  • Compound Semiconductors
  • Crystal Growth
  • Detectors
  • Infrared Lasers
  • Laser Applications
  • Laser Materials
  • Lasers
  • Materials
  • Molecular Spectroscopy
  • Optical Materials
  • Single Crystals
  • Solid State Lasers
  • Spectra
  • Spectroscopy

Fields of Study

  • Materials science
  • Physics

Readers

  • Materials Science and Engineering.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Semiconductor Device Technology

Technology Areas

  • Biotechnology
  • Directed Energy