Measurement of S-nitrosylated Proteins in Tissues of Rats Fed Diets with Differing Levels of Nitrite

Abstract

Increased ventilation is a general response to shock that may help to maintain cardiac output by improving venous return to the heart. The central stimulus for this increase in ventilation involves the production of S-nitroso-L-cysteine from more ubiquitous precursor S-nitrothiols in the medulla of the brain. Changes in dietary nitrite and nitrate have been shown to increase tissue levels of S-nitrosothiols and to improve survival in models of myocardial infarction. We hypothesize that increased dietary intake of nitrite or nitrate will enhance the ventilatory response in hemorrhage and thereby increase the time of survival. The goal of this project was to adequate methodology for the detection of S-nitrosylated proteins in tissues. A sensitive and specific method for the detection of S-nitrosylated proteins in tissues based on photolysis/immuno-spin-trapping analysis of DMPO thioethers has been developed. The applicability of the method for the quantitative assessments of Snitrosylated proteins in tissues has been tested and confirmed. The ability of dihydrolipoic acid and lipoic acid (LA) plus lipoamide dehydrogenase and NADH to denitrosate S-nitrosocaspase 3 (CASP-SNO) and regulate apoptosis in HepG2 cells has been established.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 2011
Accession Number
ADA554290

Entities

People

  • Valerian E. Kagan

Organizations

  • University of Pittsburgh

Tags

DTIC Thesaurus Topics

  • Biochemistry
  • Biomedical Research
  • Cardiovascular Physiological Phenomena
  • Casualties
  • Cell Physiological Processes
  • Cells
  • Chemistry
  • Combat Casualty Care
  • Cysteine
  • Detection
  • Hemorrhage
  • Hemorrhagic Shock
  • Ischemia
  • Lipoic Acid
  • Myocardial Ischemia
  • Proteins
  • Vascular Diseases

Fields of Study

  • Biology

Readers

  • Cardiovascular Physiology
  • Immunology and Pathology
  • Molecular and Cellular Biochemistry