Low Work Function Csl Coatings for Enhanced Field Emission Properties

Abstract

Thin films of Cesium Iodide (CsI) were deposited by pulse laser deposition and by thermal evaporation on Si substrates and were characterized by XRD, XPS, UPS, and Kelvin probe measurements. The thermally evaporated films were found to be stoichiometric whereas the pulsed laser deposited PLD films showed the presence of a Cs/CsI mixture. The latter is supported by UPS measurements whose Fermi edge indicated the presence of a metallic component (elemental Cs). The presence of a CsI/Cs mixture is also supported by the Kelvin probe work function values found to be in the range of 2.6-2.8 eV, a value in excess of the 2.1 eV reported for elemental Cs. This paper addresses the physical mechanisms responsible for the presence of the elemental Cs in the films and its ramification to their field emission properties.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 2011
Accession Number
ADA559025

Entities

People

  • D. Shiffler
  • M. Cahay
  • P. T. Murray
  • Steven B. Fairchild
  • T. C. Back

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Detectors
  • Diffraction
  • Emission
  • Evaporation
  • Field Emission
  • Films
  • High Resolution
  • Materials
  • Materials Science
  • Measurement
  • Pulsed Lasers
  • Spectra
  • Spectroscopy
  • Thin Films
  • Work Functions

Fields of Study

  • Physics

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.
  • Superconducting Magnet Technology

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition