Effect of Defect-Rich Epitaxy on Crystalline Silicon / Amorphous Silicon Heterojunction Solar Cells and the Use of Low-Mobility Layers to Improve Performance

Abstract

We present two-dimensional device physics simulations of amorphous silicon / crystalline silicon heterojunction solar cells to explain the effects of full and localized epitaxial layers, sometimes observed in the early stages of amorphous Si deposition, on cell performance. Minimizing the defect density, thickness, and wafer area fraction covered by the epitaxial region are shown to be important factors for maximizing cell open circuit voltage. We find that localized defect-rich epitaxial patches covering small percentages of the wafer surface (~5%) can cause significant reduction in open circuit voltage, which is explained by considering lateral carrier flow in the device. We also show that a thin layer of low-mobility material such as microcrystalline silicon, included between the wafer and amorphous regions can impede lateral carrier flow and improve conversion efficiencies in cases where isolated defective pinholes limit device performance.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 2011
Accession Number
ADA561147

Entities

People

  • Harry Atwater
  • Michael G. Deceglie

Organizations

  • California Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Band Structures
  • Carrier Mobility
  • Cells
  • Chemical Vapor Deposition
  • Conversion
  • Current Density
  • Efficiency
  • Electrical Properties
  • Geometry
  • Heterojunctions
  • Inclusions
  • Mobility
  • Optical Properties
  • Simulations
  • Solar Cells
  • Thickness
  • Two Dimensional

Fields of Study

  • Materials science

Readers

  • Powder metallurgy of Titanium alloys.
  • Semiconductor Device Technology
  • Solar Photovoltaics and Thermoelectric Devices.