High Power Optical Coatings by Atomic Layer Deposition and Signatures of Laser-Induced Damage

Abstract

This report describes an investigation of the properties of optical coating oxides deposited by atomic layer deposition. Specifically, two oxides were chosen as indicative of the group as a whole: aluminum oxide (Al2O3) and hafnium oxide (HfO2). Uniform films and nanolaminates (films with inserted layers of alternate materials) were deposited and tested for thermal conductivity. absorption, and laser damage threshold, among other properties. Significant effort went into the analysis of the thermal conductivities of the films since thermal breakdown is particularly relevant to directed energy applications. The interface thermal resistance in hafnia-alumina nanolaminates is very low and does not dominate the film thermal conductivity. The degree of crystallinity of these films appears to have a much larger effect on thermal conductivity than that of interface density. Cryogenic measurements show partial agreement with both the minimum thermal conductivity model for disordered solids and the diffuse mismatch model of interface resistance. Absorption measurements show results less than or near 1ppm, which matches or exceeds the performance of the best films deposited by other methods.

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Document Details

Document Type
Technical Report
Publication Date
Aug 28, 2012
Accession Number
ADA564804

Entities

People

  • Joseph J. Talghader

Organizations

  • University of Minnesota

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aluminum Oxides
  • Amorphous Materials
  • Crystal Lattice Vibrations
  • Crystal Lattices
  • Crystal Structure
  • Crystals
  • Diffraction
  • Directed Energy Weapons
  • Films
  • Laser Damage
  • Lasers
  • Materials
  • Materials Science
  • Measurement
  • Optical Coatings
  • Optical Materials
  • Thermal Conductivity

Fields of Study

  • Materials science

Readers

  • Spectroscopy.
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition